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Ammonia and methanol are both future fuels with carbon-neutral potential. Ammonia has a high octane number, a slow flame speed, and a narrow ignition limit, while methanol has a fast flame speed with complementary combustion characteristics but is more likely to lead to pre-ignition and knock. In this paper, the combustion and emission characteristics of ammonia-methanol solution in a high compression ratio spark ignition engine are investigated. The experimental results show that the peak in-cylinder pressure and peak heat release rate of the engine when using ammonia-methanol solution are lower and the combustion phase is retarded compared with using methanol at the same spark timing conditions. Using ammonia-methanol solution in the engine resulted in a more ideal combustion phase than that of gasoline, leading to an increase in indicated thermal efficiency of more than 0.6% and a wider range of efficient operating conditions.

Occurrence of sporadic super-knock is the main obstacle to the development of advanced gasoline engines. One of the possible inducements of super-knock, agglomerated soot particle induced pre-ignition, was studied for high boosted gasoline direct injection (GDI) engines. The correlation between soot emissions and super-knock frequency was investigated in a four-cylinder gasoline direct injection production engine. The test results indicate that higher in-cylinder soot emission correlate with more pre-ignition and super-knock cycles in a GDI production engine. To study the soot/carbon particles trigger super-knock, a single-cylinder research engine for super-knock study was developed. The carbon particles with different temperatures and sizes were introduced into the combustion chamber to trigger pre-ignition and super-knock.

A new combustion mode namely multiple premixed compression ignition (MPCI) for gasoline engines was proposed. The MPCI mode can be realized by two or more times gasoline injections into cylinder with a high pressure around the compression TDC and featured with a premixed combustion after each injection in the cylinder, which is different from the existed gasoline direct injection compression ignition (GDICI) modes such as homogeneous charge compression ignition (HCCI) mode with gasoline injection occurred in intake stroke, and partially premixed compression ignition (PPCI) mode with multiple gasoline injections in intake and compression strokes before the start of combustion (SOC). Therefore the spray and combustion of the MPCI mode are alternatively occurred as "spray-combustion-spray-combustion" near the TDC, rather than "spray-spray-combustion" sequence as traditional PPCI gasoline engines.

Dieseline combustion as a concept combines the advantages of gasoline and diesel by offline or online blending the two fuels. Dieseline has become an attractive new compression ignition combustion concept in recent years and furthermore an approach to a full-boiling-range fuel. High speed imaging with near-parallel backlit light was used to investigate the spray characteristics of dieseline and pure fuels with a common rail diesel injection system in a constant volume vessel. The results were acquired at different blend ratios, and at different temperatures and back pressures at an injection pressure of 100MPa. The penetrations and the evaporation states were compared with those of gasoline and diesel. The spray profile was analyzed in both area and shape with statistical methods. The effect of gasoline percentage on the evaporation in the fuel spray was evaluated.

Super-knock has been a significant obstacle for the development of highly turbocharged (downsized) gasoline engines with spark ignition, due to the catastrophic damage super-knock can cause to the engine. According to previous research by the authors, one combustion process leading to super-knock may be described as hot-spot induced pre-ignition followed by deflagration which can induce detonation from another hot spot followed by high pressure oscillation. The sources of the hot spots which lead to pre-ignition (including oil films, deposits, gas-dynamics, etc.) may occur sporadically, which leads to super-knock occurring randomly at practical engine operating conditions. In this study, a spark plasma was used to induce preignition and the correlation between super-knock combustion and the thermodynamic state of the reactant mixture was investigated in a four-cylinder production gasoline engine.

Low Speed Pre-Ignition (LSPI), also referred to as superknock or mega-knock is an undesirable turbocharged engine combustion phenomenon limiting fuel economy, drivability, emissions and durability performance. Numerous researchers have previously reported that the frequency of Superknock is sensitive to engine oil and fuel composition as well as engine conditions in controlled laboratory and engine-based studies. Recent studies by Toyota and Tsinghua University have demonstrated that controlled induction of particles into the combustion chamber can induce pre-ignition and superknock. Afton and Tsinghua recently developed a multi-physics approach which was able to realistically model all of the elementary processes known to be involved in deposit induced pre-ignition. The approach was able to successfully simulate deposit induced pre-ignition at conditions where the phenomenon has been experimentally observed.

Compressed Natural Gas (CNG), because of its low cost, high H/C ratio, and high octane number, has great potential in automotive industry, especially for heavy-duty commercial vehicles. However, relative slow flame speed of natural gas leads to long combustion duration and low thermal efficiency and tends to cause knock combustion at high load, which will aggravate engine thermal load and reliability. Enhancing turbulence intensity in combustion chamber is an effective way to accelerate flame propagation speed and improve combustion performance. In this study, the flow simulations of several piston bowls with different inner-convex forms were carried out using three-dimensional computational fluid dynamics (3D-CFD) software CONVERGE. The numerical results showed the piston bowls with inner-convex could disturb the charge swirl motion and enhance turbulence of different intensity. A hexagram geometry bowl was proved to have the best function in strengthening turbulence intensity.

Gasoline Compression Ignition has been widely studied in recent years. The in-cylinder stratified charge in gasoline Partially Premixed Compression Ignition (PPCI) can extend the high load range with lower pressure rise rate than Homogeneous Charge Compression Ignition (HCCI). However, it is still not clear that whether there is flame propagation in the gasoline compression igntion mode and how the flame propagation influences the combustion process and pollution formation. In order to investigate the effect of flame, several gasoline compression ignition cases, including the single-stage and two-stage heat release processes, are simulated with the KIVA-3V Release 2 code in this study. The G-equation is employed to account for flame propagation, and the reduced i-octane/n-heptane mechanism is used to handle the chemical reactions. The results show that the flame propagation exists in the combustion process and it can accelerate the heat release slightly.

This study uses Fourier analysis to investigate the relationship between the heat release event and the frequency composition of pressure oscillations in a variety of combustion modes. While kinetically-controlled combustion strategies such as HCCI and RCCI offer advantages over CDC in terms of efficiency and NOX emissions, their operational range is limited by audible knock and the possibility of engine damage stemming from high pressure rise rates and oscillations. Several criteria such as peak pressure rise rate, ringing intensity, and various knock indices have been developed to quantify these effects, but they fail to capture all of the dynamics required to form direct comparisons between different engines or combustion strategies. Experiments were performed with RCCI, HCCI, and CDC on a 2.44 L heavy-duty engine at 1300 RPM, generating a significant diversity of heat release profiles.

The ignition of lubricating oil droplet has been proved to be the main factor for pre-ignition and the following super-knock in turbocharged gasoline direct injection engine. In this paper, the ignition process of lubricating oil droplet in combustible ambient gaseous mixture was investigated in a rapid compression machine (RCM). The pre-ignition induction by oil droplet of the ambient gaseous mixture was analyzed under different initial droplet volume and effective temperature conditions. The oil droplet was suspended on a tungsten fiber in the combustion chamber and the ignition process was recorded by a high-speed camera through the quartz window mounted at the end of the combustion chamber. The pressure traces were also obtained by a sensor in order to get the ignition delay and analyze the combustion process in detail.

High boost and direct injection hold the potential of enhanced power density and fuel consumption in the development of gasoline engines. However, super-knock with strong destructiveness was widely reported at low-speed and high-load operating regime in turbocharged GDI engines. The objective of this study is to clarify the characteristics of super-knock and to try to find some feasible solutions to suppress super-knock. To fast evaluate super-knock at low-speed and high-load regime, a rapid test procedure including three super-knock test sections of 5000 cycles with 3 idle operations, was proposed. The experimental data indicate that pre-ignition is not the sufficient condition for super-knock. Pre-ignition may lead to super-knock, heavy knock, slight knock, and non-knock. Compared with conventional knock, knock intensity of super-knock is much higher and the maximum amplitude of pressure rise at start of knock is more than one order of magnitude higher.

A study of Multiple Premixed Compression Ignition (MPCI) with mixtures of gasoline and diesel is performed on a light-duty single cylinder diesel engine. The engine is operated at a speed of 1600rpm with the same fuel mass per cycle. By keeping the same intake pressure and EGR ratio, the influence of different blending ratios in gasoline and diesel mixtures (90vol%, 80vol% and 70vol% gasoline) is investigated. Combustion and emission characteristics are compared by sweeping the first (−95 ∼ −35deg ATDC) and the second injection timing (−1 ∼ 9deg ATDC) with an injection split ratio of 80/20 and an injection pressure of 80MPa. The results show that compared with diesel combustion, the gasoline and diesel mixtures can reduce NOx and soot emissions simultaneously while maintaining or achieving even higher indicated thermal efficiency, but the HC and CO emissions are high for the mixtures.

Knocking is the main obstacle of increasing compression ratio to improve the thermal efficiency of gasoline engines. In this paper, the concept of stratified stoichiometric mixture (SSM) was proposed to suppress knocking in gasoline engines. The rich mixture near the spark plug increases the speed of the flame propagation and the lean mixture in the end gas suppresses the auto ignition. The overall air/fuel ratio keeps stoichiometric to solve the emission problem using three way catalysts (TWC). Moreover, both the rich zone and lean zone lead to soot free combustion due to homogeneous mixture. The effect on the knocking of homogeneous and stratified mixture was studied in a direct injection spark ignition (DISI) engine using numerical simulation and experimental investigation respectively.

Multi-mode combustion is an ideal combustion strategy to utilize HCCI for internal combustion engines. It combines HCCI combustion mode for low-middle load and traditional SI mode for high load and high speed. By changing the cam profiles from normal overlap for SI mode to the negative valve overlap (NVO) for HCCI mode, as well as the adjustment of direct injection strategy, the combustion mode transition between SI and HCCI was realized in one engine cycle. By two-step cam switch, the throttle action is separated from the cam action, which ensures the stabilization of mode transition. For validating the feasibility of the stepped switch, the influence of throttle position on HCCI combustion was carefully studied. Based on the research, the combustion mode switch was realized in one engine cycle; the whole switch process including throttle action was realized in 10 cycles. The entire process was smooth, rapid and reliable without any abnormal combustion such as knocking and misfiring.

The detailed chemical kinetics was implemented into the 0D single-zone model, 1D engine cycle model and 3D CFD model respectively. Both simulation and experiment were carried out on a four-stroke gasoline HCCI engine with direct injection. The 0D model (HRG) was developed to study the isolating effect of HCCI parameters. The 1D engine cycle model with HRG was established to study the gas exchange process and the direct injection strategy in the gasoline HCCI engine with two-stage direct injection (TSDI) and negative valve overlap (NVO). The 3D model with HRG was constructed to study the ignition control mechanism in “two-zone HCCI” combustion via analysis the auto-ignition spots distribution in combustion chamber. “Two-zone HCCI” is defined in this paper as premixed ultra-lean compression ignition combining with premixed ultra-rich compression ignition. The three models were validated by experiments.

This study improved the computational efficiency significantly using parallel computation and reduced mechanisms. A 3-dimensional engine moving mesh of intake port, exhaust port and combustion chamber was established for HCCI engine cycle simulation. To achieve a more accurate analysis, chemical kinetics was implemented into the CFD code to study the intake, spray, ignition, combustion, and pollution formation process in HCCI engine. The simulations were run on a cluster of 16-CPU, parallelized by Message-Passing Interface (MPI) mode. The cases with detailed and reduced reaction mechanisms were calculated using 1, 2, 4, 8, 16 CPUs respectively and the corresponding computational time and speed-up were discussed. Using MPI 8-CPU with reduced mechanism (less than 40 species) is the optimal scheme for CFD/Chemistry calculation of typical HCCI engine.

Ammonia (NH3), a zero-carbon fuel, has great potential for internal combustion engine development. However, its high ignition energy, low laminar burning velocity, narrow range of flammability limits, and high latent heat of vaporization are not conducive for engine application. This paper numerically investigates the feasibility of utilizing ammonia in a heavy-duty diesel engine, specifically through low-pressure direct injection (LP-DI) of hydrogen to ignite ammonia combustion. Due to the lack of a well-corresponding mechanism for the operating conditions of ammonia-hydrogen engines, this study serves only as a trend-oriented prediction. The paper compares the engine's combustion and emission performance by optimizing four critical parameters: excess air ratio, hydrogen energy ratio, ignition timing, and hydrogen injection timing. The results reveal that excessively high hydrogen energy ratios lead to an advanced combustion phase, reducing indicated thermal efficiency.

Homogeneous Charge Induced Ignition (HCII) combustion is believed to be a promising approach to achieve clean and high efficiency combustion. HCII can be realized by using port-injection of the high-volatile fuel (gasoline) to prepare in-cylinder homogeneous charge and direct injection of the high-ignitable fuel (diesel) near the top dead center to control the start of combustion. In the current study, a numerical study was carried out to understand the mixing and auto-ignition process in HCII combustion. A multicomponent chemical kinetic mechanism for gasoline and diesel, consisting of n-heptane, iso-octane, ethanol, toluene, diisobutylene and n-decane, has been developed for predicting their ignition and oxidation. The final mechanism consists of 104 species and 398 reactions. This mechanism was validated with the experimental data of ignition delay times and laminar flame speeds for each component and real transportation fuels.

Ammonia shows promise as an alternative fuel for internal combustion engines (ICEs) in reducing CO2 emissions due to its carbon-free nature and well-established infrastructure. However, certain drawbacks, such as the high ignition energy, the narrow flammability range, and the extremely low laminar flame speed, limit its widespread application. The dual fuel (DF) mode is an appealing approach to enhance ammonia combustion. The combustion characteristics of ammonia-diesel dual fuel mode and ammonia-PODE3 dual fuel mode were experimentally studied using a full-view optical engine and the high-speed photography method. The ammonia energy ratio (ERa) was varied from 40% to 60%, and the main injection energy ratio (ERInj1) and the main injection time (SOI1) were also varied in ammonia-PODE3 mode.

A computational fluid dynamics (CFD) guided design optimization was conducted for the piston bowl geometry for a heavy-duty diesel engine. The optimization goal was to minimize engine-out NOx emissions without sacrificing engine peak power and thermal efficiency. The CFD model was validated with experiments and the combustion system optimization was conducted under three selected operating conditions representing low speed, maximum torque, and rated power. A hundred piston bowl shapes were generated, of which 32 shapes with 3 spray angles for each shape were numerically analyzed and one optimized design of piston bowl geometry with spray angle was selected. On average, the optimized combustion system decreased nitrogen oxide (NOx) emissions by 17% and soot emissions by 41% without compromising maximum engine power and fuel economy.